La Montagne Sainte-Victoire by Paul Cezanne, from the Paul G. Allen Collection. AP

The two-day sale in New York comes as experts say the super wealthy are viewing art as a safe investment this year amid a tumultuous global economy and Russia's war in Ukraine.

Allen made his fortune with the establishment of the PC operating system with his better-known Microsoft co-founder Bill Gates in 1975.

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He amassed a huge art collection which he used to lend to museums before his death in 2018 at the age of 65.

The 150 works, to be sold Wednesday and Thursday at Christie's Manhattan headquarters, trace more than 500 years of art history, from Botticelli and Canaletto to Georgia O'Keeffe and Louise Bourgeois, via Claude Monet, Francis Bacon and Edward Hopper.

The collection is also unique for its value: several masterpieces are estimated to fetch more than $100 million.

Microsoft co-founder Paul Allen

They include French painter Paul Cezanne's "Montagne Sainte-Victoire" (1888-1890), which heralded cubism, and Georges Seurat's 1888 work "Les Poseuses, Ensemble (small version)", a renowned work of pointillism.

Also going under the gavel is Vincent Van Gogh's "Orchard with Cypresses" and a painting from Paul Gauguin's Tahitian period, "Maternity II" (1899), which controversially depicts his teenage mistress, Pahura.

Allen left Microsoft in 1983, due to health problems and a deteriorating relationship with Gates, who remained in charge of the company until 2000.

Despite their strained friendship, Allen signed Gates's "Giving Pledge" campaign and all proceeds from the auction are to be donated to charity.

Christie's hopes the total sales will become part of art market history and top $1 billion.

The current auction record for a private collection was set this spring by the US couple Harry and Linda Macklowe, with $922 million fetched in auctions conducted by Sotheby's.

Agence France-Presse