The Brave Commander bulk carrier makes its way from the Pivdennyi Seaport near Odesa, Ukraine, on Tuesday. Reuters

The MV Brave Commander left the Black Sea port of Pivdennyi and will sail to Djibouti "for delivery to Ethiopia", the infrastructure ministry said on Telegram. The ship is carrying 23,000 tonnes of wheat.

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It is the first ship chartered by the UN World Food Programme (WFP) to leave Ukraine since the start of the Russian invasion in February and the government has said it hopes two or three similar shipments will follow soon.

Ukraine and Russia are two of the world's biggest grain exporters.

Kyiv and Moscow agreed a deal brokered by the UN and Turkey last month to unblock Black Sea grain deliveries after Russia's invasion.

The agreement lifted a Russian blockade of Ukraine's ports and established safe corridors through the naval mines laid by Kyiv.

The Ukrainian port authority said that five boats in total with an overall cargo volume of 110,000 tonnes had left Ukraine on Tuesday.

The first commercial ship carrying grain left on August 1. Since then, 21 ships have left Ukrainian ports, the port authority said in its statement.

The WFP says a record 345 million people in 82 countries face acute food insecurity and up to 50 million people in 45 countries are on the brink of famine and risk being tipped over the edge without humanitarian support.

Agence France-Presse